According to media reports in Italy, the deal will be worth €15million when completed.
The 26-year-old Ghana international spent his entire playing career in Italy, starting from the Inter academy in 2010, going on to Livorno, Sampdoria and since the summer of 2015 at Sassuolo.A rugged midfielder, he has contributed one goal and five assists in 13 Serie A games this season.
Duncan already worked with coach Beppe Iachini at Sassuolo in 2017-18.
He has made eight appearances for Ghana's senior national team.